STUDY OF FIRE PROTECTION PROPERTIES OF INTUMESCENT ROLL COATINGS
DOI:
https://doi.org/10.32782/naturaljournal.12.2025.10Keywords:
fire protection, intumescent coating, expandable graphite, swollen graphite, foam char, roll materialsAbstract
Ensuring effective and rapid fire protection of building structures, infrastructure and defence facilities requires the use of efficient, technologically advanced mobile means. Intumescent roll coatings are of particular relevance, as they are capable of providing constructive and reactive fire protection through the interaction of fibre substrate and special compositions. These coatings are flexible, easy to apply and adaptable to different operating conditions. The purpose of the study is to investigate the effect of graphite fillers on the fire protection efficiency of roll intumescent fire protection materials based on different types of inorganic substrates (glass fibre, mineral fibre, ceramic fibre). The methods of the experiment were the preparation of compositions based on the ammonium polyphosphate (APP)/ melamine (MA)/pentaerythritol (PE) system with the variable addition of expandable (EG) and swollen graphite (SG), the formation of roll coatings, and fire tests using the Bunsen burner method. The necessity of combining graphite fillers with an intumescent system to achieve effective fire protection characteristics of reactive roll coatings has been proved. The study found that the most effective compositions contain EG – no more than 5%, SG – no more than 1%, and also include a glass fibre mesh as a reinforcing element. Such coatings provide stable intensive swelling, formation of a homogeneous char layer and effective thermal insulation. The scientific novelty lies in the comprehensive analysis of the influence of formulation parameters on the thermal insulation properties of coatings, which allows for a targeted approach to the design of the composition of the intumescent coating with specified fire resistance indicators. The practical significance of the study is based on the possibility of implementing the developed roll of mobile fire protection products, the production of which is not available in Ukraine.
References
Аmir N., Ahmad F., Megat-Yusoff P.S.M. Study on the Fibre Reinforced Epoxy-Based Intumescent Coating Formulations and their Char Characteristics. Journal of Applied Sciences. 2011. Vol. 11. P. 1678–1687. https://doi.org/10.3923/jas.2011.1678.1687.
Amir N., Ahmad F., Megat Yusoff P.S.M. Char Strength of Wool Fibre Reinforced Epoxy-Based Intumescent Coatings (FRIC). Advanced Materials Research. 2013. Vol. 626. P. 504–508. https://doi.org/10.4028/www.scientific.net/AMR.626.504.
Brent K.M., T’ien J.S. Performance optimization of thin fire blankets by varying their radiative properties. Journal of Fire Sciences. 2022. Vol. 40 (1). P. 26–43. https://doi.org/10.1177/07349041211050328.
Chin W.K., Mulkern T.J., Tewarson A. Fire-Resistant and Fragment Penetration-Resistant Blankets for the Protection of Stored Ammunition. Aberdeen Proving Ground, MD: Army Research Laboratory, 2000. 71 p. [Електронний ресурс]. URL: https://archive.org/details/DTIC_ADA383514/page/n3/mode/2up (дата звернення: 14.03.2025).
Gernay T. Performance-based design for structures in fire: Advances, challenges, and perspectives. Fire Safety Journal. 2024. Vol. 142. 104036. https://doi.org/10.1016/j.firesaf.2023.104036.
Gravit M., Korolchenko D., Nedviga E., Portnov F., Diachenko S. Impact of jet fires on steel structures: application of passive fire protection materials. Fire. 2024a. Vol. 7. 281. https://doi.org/10.3390/fire7080281.
Gravit M., Prusakov V., Shcheglov N., Kotlyarskaya I. Fire protection of steel structures of oil and gas facilities: multilayer, removable, non-combustible covers. Fire. 2024b. No. 7. 86. https://doi.org/10.3390/fire7030086.
Kalafat K., Taran N., Plavan V., Bessarabov V., Zagoriy G., Vakhitova L. Comparison of fire resistance of polymers in intumescent coatings for steel structures. Eastern- European Journal of Enterprise Technologies. 2020. No. 4 (10 (106)). P. 45–54. https://doi.org/10.15587/1729-4061.2020.209841.
Kmeťová E., Kačíková D., Kačík F. The Effect of intumescent coating containing expandable graphite onto spruce wood. Coatings. 2024. Vol. 14. 490. https://doi.org/10.3390/coatings14040490.
Ma L., Song Q., Dong F., Yang H., Xia Z., Liu J. Effect of organic–inorganic mixed intumescent flame retardants on fire-retardant coating. Coatings. 2024. Vol. 14. 1034. https://doi.org/10.3390/coatings14081034.
Nolan D.P. Handbook of Fire and Explosion Protection Engineering Principles for Oil, Gas, Chemical, and Related Facilities. Westwood: Noyes Publications, 2019. 426 p.
Otáhal R., Veselý D., Násadová J., Zíma V., Němec P., Kalenda P. Intumescent coatings based on an organic-inorganic hybrid resin and the effect. Pigment & Resin Technology. 2011. Vol. 40 (4). P. 247–253. https://doi.org/10.1108/0369942111114732613.
Shiu B.C., Huang C.H., Yang H.L., Chen Y.S., Lou C.W., Lin J.H. Construction sheets made of high-performance flame-retardant nonwoven fabrics and combustion-resistant polyurethane foam: preparation process and property evaluations. Polymers. 2023. Vol. 15 (4). 953. https://doi.org/10.3390/polym15040953.
Steau E., Mahendran M., Poologanathan K. Experimental study of fire resistant board configurations under standard fire conditions. Fire Safety Journal. 2020. Vol. 116. 103153. https://doi.org/10.1016/j.firesaf.2020.103153.
Takahashi F. Fire blanket and intumescent coating materials for failure resistance. MRS Bulletin. 2021. Vol. 46. P. 429–434. https://doi.org/10.1557/s43577-021-00102-7.
Tewarson A., Wu P.K., Chin W.K., Shuford R. Fire Blankets for Munition Protection: Flame and Heat Blocking Properties of Advanced Materials. Army Research Laboratory, 2001. 55 p. [Електронний ресурс]. URL: https://apps.dtic.mil/sti/tr/pdf/ADA387272.pdf (дата звернення: 12.02.2025).
Triantafyllidis Z., Bisby L. A. Fibre-reinforced intumescent fire protection coatings as a confining material for concrete columns. Construction and Building Materials. 2020. Vol. 231. 117085. https://doi.org/10.1016/j.conbuildmat.2019.117085.
Vakhitova L., Kalafat K., Vakhitov R., Drizhd V. Improving the fire-retardant performance of industrial reactive coatings for steel building structures. Heliyon. 2024. Vol. 10. e34729. https://doi.org/10.1016/j.heliyon.2024.e34729.
Wang K., Le H. The development of cement-based, intumescent and geopolymer fire-retardation coatings for metal structures: a review. Coatings. 2023. Vol. 13. 495. https://doi.org/10.3390/coatings13030495.
Yasir M., Ahmad F., Yusoff P.S.M.M., Ullah S., Jimenez M. Latest trends for structural steel protection by using intumescent fire protective coatings: a review. Surface Engineering. 2019. Vol. 36 (4). P. 334–363. https://doi.org/10.1080/02670844.2019.1636536.
Zheng Z., Liu Y., Zhang L., Wang H. Synergistic effect of expandable graphite and intumescent flame retardants on the flame retardancy and thermal stability of polypropylene. Journal of Materials Science. 2016. Vol. 51 (12). P. 5857–5871. https://doi.org/10.1007/s10853-016-9887-6.